NOx Reduction
CRI Selective Catalytic (SCR) NOx Reduction Technology
Since its commercial introduction in the 1970's, Selective
Catalytic Reduction (SCR) of nitrogen oxides (NOx) has gained
wide acceptance worldwide as the most effective and technologically
proven method for high-percentage NOx removal from flue gases.
CRI's technology, known as the Shell DeNOx System (SDS), operates
on the SCR principal. It uses ammonia (NH 3) as the reductant
and a catalyst to promote the reaction of NH 3 with NOx,
forming nitrogen and water.
An efficient retrofit
The CRI SCR catalyst can operate at lower temperatures and
with lower pressure drop than conventional SCR catalysts.
Consequently, the CRI SCR system can be installed immediately
before or in the stack, thereby avoiding any modifications
to combustion or heat-recovery equipment or negative effects
on other upstream plant operations. This makes the CRI technology
very cost-effective for retrofit SCR applications.
| Typical
Application Conditions and Performance of the CRI Low-Temperature
SCR Technology: |
| |
| Operating Temperature |
|
Typical Application |
325-450° F /160-230° C |
|
Range |
300-700° F/
150-375° C |
| Pressure Drop |
|
Typical Application |
2-3 in. H2O/ 5-7.5
mbar |
|
Range |
As low as 1 in. H2O/2.5
mbar |
| Performance |
|
NOx Conversion |
>90% |
|
NH3 Slip |
5-10 ppm or lower |
Unique catalyst and module technology
The CRI technology differs from conventional SCR systems in
two important aspects: the catalyst and the catalyst reactor
module. The catalyst is in the form of pellets and can be
produced in a range of sizes and shapes to meet specific
performance requirements. Due to the high activity of the
catalyst, high NOx removal efficiencies with simultaneous
control of NH 3 slip can be obtained at relatively low temperatures.
The catalyst reactor module is based on the Lateral Flow Reactor
(LFR) principal. The LFR is a packed-bed type reactor which
offers the advantage of low pressure drop even at high space
velocities. Furthermore, the LFR design makes possible the
most efficient utilization of the SCR catalyst, which minimizes
the amount of catalyst required and facilitates fast loading
and unloading of catalyst from the reactor.
Development of the LFR technology has resulted in a modular
construction system, providing a high degree of flexibility
in the design of SCR systems for specific applications, particularly
retrofit.
A broad range of applications
The CRI SCR technology has been successfully applied to combustion
and chemical process operations including gas turbines, refinery
heaters, boilers, ethylene cracker furnaces, nitric acid
plants and waste incineration facilities.
Resulting from the high catalyst activity and flexibility of the
LFR module design, the optimal and most cost-effective combination
of
NOx removal, NH 3 slip, temperature, pressure drop and available
plot or duct space can be developed for virtually any application.